Supporting Information “Specific Solvation Interactions of CO2 on Acetate and Trifluoroacetate Imidazolium Based Ionic Liquids at High Pressures”
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Specific solvation interactions of CO2 on acetate and trifluoroacetate imidazolium based ionic liquids at high pressures.
New classes of acidic or basic ionic liquids (ILs) are gaining special attention, since the efficiency of many processes can be enhanced by the judicious manipulation of these properties. The absorption of sour gases can be enhanced by the basic character of the IL. The fluorination of the cation or the anion can also contribute to enhance the gas solubility. In this work these two characterist...
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The ferrocene/ferrocenium (Fc/Fc(+)) redox couple has been deemed one of the best candidates of the standard electrochemical reference for redox reactions in ionic liquids (ILs). To fully reveal the redox reaction mechanism in the IL condensed phase, solvation, as a prerequisite, apparently needs to be understood. As a preliminary attempt to study the solvation of Fc/Fc(+) in imidazolium-based ...
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